At least from what I've heard that's because stdint values are optional.
6.2.5p17
The three types char, signed char, and unsigned char are collectively called the character types.
The implementation shall define char to have the same range, representation, and behavior as either
signed char or unsigned char.
48)
and
5.2.4.2.1 says that width of char, signed char and unsigned char are the same (8).
A conforming implementation could extend the language with an 8-bit type __nonaliasingbyte which has no special aliasing privileges, and define uint8_t as being synonymous with that type.
On the other hand, the Standard should never have given character types special aliasing rules to begin with. Such rules would have been unnecessary if the Standard had noted that an access to an lvalue which is freshly visibly derived from another is an access to the lvalue from which it is derived. The question of whether a compiler recognizes a particular lvalue as "freshly visibly derived" from another is a Quality of Implementation issue outside the Standard's jurisdiction.